REACTION OF DICHLOROCARBENE WITH 1,2-DIHYDRO 1,2-LAMBDA-3-AZAPHOSPHININE-BORANES - DICHLOROCYCLOPROPANATION AND INSERTION INTO BORON HYDROGEN-BOND

被引：25

作者：

BEDEL, C ^{[1
]}

FOUCAUD, A ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,PHYSICOCHIM STRUCT LAB,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 02期

关键词：

PHOSPHINE-BORANES; CYCLOPROPANATION; CARBENE INSERTION INTO B-H BOND;

D O I：

10.1016/S0040-4039(00)60575-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of dichlorocarbene with 1,2-dihydro 1,2 lambda3-azaphosphinine-boranes gave regioselective dichlorocyclopropanation and also insertion of dichlorocarbene into B-H bond. This insertion reaction is general and can be a useful synthetic method for the preparation of functionalized phosphine-boranes.

引用

页码：311 / 314

页数：4

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