POTENTIAL-ENERGY SURFACES OF ONE-WAY AND 2-WAY PHOTOISOMERIZATION OF OLEFINS

被引：38

作者：

TOKUMARU, K

ARAI, T

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1992年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/1010-6030(92)85026-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mechanisms of "mutual two-way and newly discovered one-way isomerization are discussed for various types of olefins in terms of their experimentally determined triplet potential energy surfaces.

引用

页码：1 / 13

页数：13

共 58 条

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ARAI, T ;

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SAKURAGI, H ;

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ARAI, T ;

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SAKURAGI, H ;

TOKUMARU, K .

CHEMICAL PHYSICS LETTERS, 1988, 149 (02) :161-166

[3] NOVEL INSIGHTS INTO PHOTOISOMERIZATION OF OLEFINS [J].

ARAI, T ;

KARATSU, T ;

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SAKURAGI, H ;

TOKUMARU, K .

PURE AND APPLIED CHEMISTRY, 1988, 60 (07) :989-998

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ARAI, T ;

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CHEMICAL PHYSICS LETTERS, 1989, 157 (1-2) :46-50

[5] CONFORMATIONS OF THE TRIPLET-STATE OF AROMATIC OLEFINS - OBSERVATION OF THE TRANSOID TRIPLET-STATES OF 3,3-DIMETHYL-1-(2-NAPHTHYL)-1-BUTENE AND 3,4-DIHYDROPHENANTHRENE AS A RIGID PLANAR TRIPLET MODEL [J].

ARAI, T ;

SAKURAGI, H ;

TOKUMARU, K ;

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NAKAMURA, J ;

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CHEMICAL PHYSICS LETTERS, 1983, 98 (01) :40-44

[6] PHOTOSENSITIZED CIS-TRANS ISOMERIZATION OF BETA-ALKYLSTYRENES [J].

ARAI, T ;

SAKURAGI, H ;

TOKUMARU, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (07) :2204-2207

[7] ONE-WAY PHOTO-ISOMERIZATION BETWEEN CIS-OLEFIN AND TRANS-OLEFIN - A NOVEL ADIABATIC PROCESS IN THE EXCITED-STATE [J].

ARAI, T ;

KARATSU, T ;

SAKURAGI, H ;

TOKUMARU, K .

TETRAHEDRON LETTERS, 1983, 24 (28) :2873-2876

[8] EFFECT OF OXYGEN ON THE PHOTOSTATIONARY STATE COMPOSITION IN TRIPLET SENSITIZED CIS-TRANS ISOMERIZATION OF 1-ARYL-3,3-DIMETHYL-1-BUTENES - A CLASSIFICATION OF TRIPLET ENERGY SURFACES OF AROMATIC OLEFINS [J].

ARAI, T ;

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TOKUMARU, K .

CHEMISTRY LETTERS, 1981, (10) :1377-1380

[9] EFFECT OF OXYGEN ON THE PHOTOSTATIONARY STATE COMPOSITION IN TRIPLET SENSITIZED ISOMERIZATION OF 3,3-DIMETHYL-1-(2-NAPHTHYL)-1-BUTENE [J].

ARAI, T ;

SAKURAGI, H ;

TOKUMARU, K .

CHEMISTRY LETTERS, 1980, (11) :1335-1338

[10] UNUSUAL BEHAVIOR OF BETA-TERT-ALKYLSTYRENES IN PHOTOSENSITIZED CIS-TRANS ISOMERIZATION - STRUCTURAL EFFECTS ON TRIPLET ENERGY-TRANSFER [J].

ARAI, T ;

SAKURAGI, H ;

TOKUMARU, K .

CHEMISTRY LETTERS, 1980, (03) :261-264

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