A PRACTICAL O2-OXIDATION OF FUNCTIONALIZED ALCOHOLS PRODUCING CARBOXYLIC-ACIDS CATALYZED BY THE PD-C/PB(OAC)2 SYSTEM

被引：14

作者：

AKADA, M ^{[1
]}

NAKANO, S ^{[1
]}

SUGIYAMA, T ^{[1
]}

ICHITOH, K ^{[1
]}

NAKAO, H ^{[1
]}

AKITA, M ^{[1
]}

MOROOKA, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 05期

关键词：

D O I：

10.1246/bcsj.66.1511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pd-C/Pb(OAc)2 system catalyzes selective O2-oxidation of ArCH(R)CH2OH to ArCH(R)COOH (useful intermediates for drug synthesis) in high yields without contamination of ArCOOH. The turnover number (substrate/Pd) is improved to 85 and >1800 by recycling the catalyst, and using a special reactor, respectively. Alkanols are also efficiently oxidized to alkanoic acids by the title catalyst system.

引用

页码：1511 / 1515

页数：5

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