SYNTHESIS OF HETEROLEPTIC BIS(AMIDES) - CRYSTAL-STRUCTURE OF THE REPRESENTATIVE COMPOUND, [(MG[N(PH)2][N(PH)(2-PYR)])2]

被引：18

作者：

HENDERSON, KW

MULVEY, RE

CLEGG, W

ONEIL, PA

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 20期

关键词：

D O I：

10.1016/S0277-5387(00)83080-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

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页码：2535 / 2538

页数：4

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