AN EPR STUDY OF A PALLADIUM CATALYST USING A PBN (N-BENZYLIDENE-TERT-BUTYLAMINE N-OXIDE) SPIN TRAP - DIRECT DEMONSTRATION OF HYDROGEN SPILLOVER

被引：19

作者：

CARLEY, AF

EDWARDS, HA

MILE, B

ROBERTS, MW

ROWLANDS, CC

JACKSON, SD

HANCOCK, FE

机构：

[1] UNIV WALES COLL CARDIFF, SCH CHEM & APPL CHEM, CARDIFF CF1 3TB, WALES

[2] ICI KATALCO, T&E GRP, BILLINGHAM TS23 1LB, CLEVELAND, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001407

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

EPR spectroscopy, in conjunction with spin trapping, is shown to provide a convenient, simple technique for detecting the dissociation of hydrogen on a supported palladium catalyst and leads to a direct demonstration of the occurrence of spillover on to the alumina support.

引用

页码：1407 / 1408

页数：2

共 9 条

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