DIPOLE PROPERTIES OF MOLECULAR HYDROGEN

被引:98
作者
VICTOR, GA
DALGARNO, A
机构
[1] GCA Technology Division, GCA Corporation, Bedford
[2] Harvard College Observatory and Smithsonian Astrophysical Observatory, Cambridge, MA
关键词
D O I
10.1063/1.1671412
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experimental data on electron scattering, optical refractivity, and molecular anisotropy are used to construct a model dipole spectrum for molecular hydrogen which is consistent with oscillator-strength sum rules. The model spectrum is used to calculate the parallel and perpendicular dynamic dipole polarizabilities, the refractive index, the Verdet constant, the Rayleigh scattering cross section, the Rayleigh depolarization factor, and the molecular anisotropy as a function of frequency of the incident radiation. The tensor components of the van der Waals coefficient for a pair of interacting hydrogen molecules are also calculated.
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页码:2535 / &
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