MONTE-CARLO SIMULATION OF MULTIPLE CHAIN SYSTEMS - 2ND MOMENT AND 4TH MOMENT

被引:39
作者
CURRO, JG
机构
[1] Sandia Laboratories, Albuquerque
关键词
D O I
10.1021/ma60069a024
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Monte-Carlo simulations were performed on concentrated systems of chains of 15 and 20 units on a tetrahedral lattice. The average second and fourth moments of the end-to-end distance were computed from these simulations. Both the second and fourth moments, when extrapolated to bulk concentration, were found to agree with ideal chain values. The scaling exponent for the concentration dependence of the second moment in the semidilute range, for these short-chain systems, was found to be less than the theoretical value of 1/4. © 1979, American Chemical Society. All rights reserved.
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页码:463 / 466
页数:4
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