FORMAL [2 + 2] AND [4 + 2] CYCLOADDITION REACTIONS OF IRON(II) ACETYLIDE COMPLEXES - X-RAY CRYSTALLOGRAPHIC STRUCTURE DETERMINATIONS OF [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE](ETA-5-CYCLOPENTADIENYL)(4,4-DIPHENYL-2-METHYL-3-OXO-1-CYCLOBUTENYL)IRON(II) AND [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE](2-CYANO-4-METHYLENE-1-CYCLOBUTENYL)(ETA-5-CYCLOPENTADIENYL)IRON(II)

被引：29

作者：

BARRETT, AGM

CARPENTER, NE

MORTIER, J

SABAT, M

机构：

[1] Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

14;

D O I：

10.1021/om00115a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iron(II) acetylide complexes 8, 12, and 13 reacted with diphenylketene, phenylethylketene, 3,3-dimethylbutanoyl chloride, 2-chloroacrylonitrile, diketene, dimethyl methylenemalonate, and 1,3-dicyano-l,3-butadiene to produce the corresponding formal [2 + 2] and [4 + 2] cycloadducts. The structures of (diphos)(Cp)FeC═C(Me)COC(Ph)2 (space group P2l/n (No. 14), Z = 4, a = 15.187 (2) Å, b = 18.548 (4) Å, c = 15.631 (2) Å,β = 109.16 (1)°, R(F) = 0.077) and (diphos)(Cp)FeC═C(CN)CH2C(═CH2) (space group Pna2l (No. 33), Z = 4, a = 18.860 (2) Å, b = 10.050 (1) Å, c = 15.733 (4) Å, R(F) = 0.038) were determined by X-ray crystallography. © 1990, American Chemical Society. All rights reserved.

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页码：151 / 156

页数：6

相关论文

共 22 条

[1] CATIONIC VINYLIDENE COMPLEXES - PREPARATION AND STRUCTURAL CHARACTERIZATION OF ETA-5-CYCLOPENTADIENYL)(2-METHYL-4,5-BIS(DIPHENYLPHOSPHINO)-2-PENTEN-3-YL)IRON (II) - BASE-INDUCED INTERLIGAND REACTION IN A VINYLIDENE COMPLEX [J].

ADAMS, RD ;

DAVISON, A ;

SELEGUE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (24) :7232-7238

[2] SYNTHESIS AND POLYMERIZATION OF THE 4 1,3-DI(CYANO AND-OR CARBOMETHOXY)-SUBSTITUTED BUTADIENES [J].

AHN, KD ;

HALL, HK .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1981, 19 (03) :629-644

[3] IRON(II) VINYLIDENES AND CHROMIUM CARBENE COMPLEXES IN BETA-LACTAM SYNTHESIS [J].

BARRETT, AGM ;

MORTIER, J ;

SABAT, M ;

STURGESS, MA .

ORGANOMETALLICS, 1988, 7 (12) :2553-2561

[4]

Bruce M. I., 1981, J CHEM SOC CHEM COMM, V271

[5] REACTIONS OF TRANSITION-METAL SIGMA-ACETYLIDES .11. CYCLO-ADDITION REACTIONS WITH 1,1-DICYANO-2,2-BIS(TRIFLUOROMETHYL)ETHENE - X-RAY STRUCTURES OF W(C=CPHC(CF3)2C(CN)2)(CO)3(ETA-C5H5), MN(C=CPHC(CF3)2C(CN)2)(CO)3(DPPE), AND FE(C=CPHC(CF3)2C(CN)2)(CO)2(ETA-C5H5) AND OF A HYDRATION PRODUCT, W(NH=C(OH)C(CN)=CCPH=C(CF3)2)(CO)2(ETA-C5H5).H2O) [J].

BRUCE, MI ;

LIDDELL, MJ ;

SNOW, MR ;

TIEKINK, ERT .

ORGANOMETALLICS, 1988, 7 (02) :343-350

[6] SOME REACTIONS OF TRANSITION-METAL COMPLEXES CONTAINING UNSATURATED LIGANDS WITH M-C(SP) OR M-C(SP2) BONDS [J].

BRUCE, MI .

PURE AND APPLIED CHEMISTRY, 1986, 58 (04) :553-560

[7]

BRUCE MI, 1983, ADV ORGANOMET CHEM, V22, P59

[8] REACTIONS BETWEEN TETRACYANOETHYLENE AND TRANSITION-METAL ACETYLIDES - FORMATION AND CLEAVAGE OF THE CYCLOBUTENYL RING IN AN AUTHENTIC TETRACYANOCYCLOBUTENYL-METAL COMPLEX, W[C=CPHC(CN)2C(CN)2] (CO)3 (ETA-C5H5) [J].

BRUCE, MI ;

HAMBLEY, TW ;

RODGERS, JR ;

SNOW, MR ;

SWINCER, AG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 226 (01) :C1-C4

[9] REACTIONS OF TRANSITION-METAL ACETYLIDES .6. SOME ADDITION-REACTIONS OF SUBSTITUTED STYRENES WITH RU(C2R)(L)2(ETA-C5H5)(R=ME OR PH-L2=(CO,PPH3), (PPH3)2 OR (DPPE)) - X-RAY CRYSTAL-STRUCTURE OF RU(C[=C(CN)2]CPH=CH(C6H4O2-4))(DPPE)(ETA-C5H5).0.5CH2CL2 [J].

BRUCE, MI ;

HUMPHREY, PA ;

SNOW, MR ;

TIEKINK, ERT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 303 (03) :417-427

[10] REACTIONS OF TRANSITION-METAL SIGMA-ACETYLIDE COMPLEXES .10. CYCLOADDITION OF TETRACYANOETHENE TO MANGANESE, IRON AND NICKEL-COMPLEXES, AND HYDRATION OF A RELATED TUNGSTEN COMPLEX - X-RAY STRUCTURES OF FE(C[=C(CN)2]CPH=C(CN)2)(CO)2(ETA-C5H5) AND NI(C[=C(CN)2]CPH=C(CN)2)(PPH3)(ETA-C5H5) [J].

BRUCE, MI ;

DUFFY, DN ;

LIDDELL, MJ ;

SNOW, MR ;

TIEKINK, ERT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 335 (03) :365-378