IMIDO LIGAND-EXCHANGE AT A MOLYBDENUM(V) CENTER

被引：22

作者：

HOGARTH, G ^{[1
]}

KONIDARIS, PC ^{[1
]}

机构：

[1] UNIV OXFORD,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 399卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)80093-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the dimolybdenum tetraimido complex [(MeC5H4)Mo(NPh)(μ-NPh)]2 with an excess of para-tolyl isocyanate results in the stepwise exchange of terminal imido ligands to yield [(MeC5H4)2Mo2(N-p-tolyl)(NPh)(μ-NPh)2] and [(MeC5H4)Mo(N-p-tolyl)(μ-NPh)]2. Prolonged heating does not, however, result in substitution of the bridging phenylimido ligands. © 1990.

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页码：149 / 152

页数：4

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