VIBRATIONAL-SPECTRA OF THE MU-2-HYDRIDE LIGANDS IN [H4M4(CO)12] (M = OS, RU)

被引：5

作者：

ANSON, CE

JAYASOORIYA, UA

KETTLE, SFA

STANGHELLINI, PL

ROSSETTI, R

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

[2] UNIV SASSARI,DIPARTIMENTO CHIM,I-07500 SASSARI,ITALY

[3] UNIV TURIN,DIPARTIMENTO CHIM INORGAN CHIM FIS & CHIM MAT,I-10125 TURIN,ITALY

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1021/ic00010a012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The vibrational spectra of the hydride ligands in the title compounds are interpreted in terms of D2d molecular symmetry. The pseudo-D4h symmetry of the four hydrides (if the rest of the cluster is neglected) and the spherical symmetry of the hydride is orbital are shown to have a profound effect on the Raman intensities of some of the hydride modes.

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页码：2282 / 2286

页数：5

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