SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR PLATINUM(II) COMPLEXES CONTAINING BOTH MU-PYRAZOLATO-N,N AND GROUP-16 DONORS (ER' - E = O, S, SE, TE) AS BRIDGING LIGANDS

被引：24

作者：

JAIN, VK ^{[1
]}

KANNAN, S ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV FUEL CHEM,BOMBAY 400085,INDIA

来源：

POLYHEDRON | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83254-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dinuclear platinum(II) complexes containing both pyrazolato-N,N and group 16 donors, of the general formula [Pt2Cl2(mu-ER')(mu-pz)(PR3)2] (E = O, S, Se, Te; R' = alkyl or aryl; pzH = pyrazole; PR3 = tertiary phosphine) have been synthesized. The complexes were characterized by elemental analyses and NMR (H-1 and P-31). The stereochemistry of the complexes has been discussed on the basis of NMR data.

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页码：27 / 31

页数：5

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