ALKENE AZIRIDINATION AND EPOXIDATION CATALYZED BY CHIRAL METAL SALEN COMPLEXES

被引：141

作者：

OCONNOR, KJ ^{[1
]}

WEY, SJ ^{[1
]}

BURROWS, CJ ^{[1
]}

机构：

[1] SUNY STONY BROOK,DEPT CHEM,STONY BROOK,NY 11974

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 08期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)91844-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New chiral metal salen complexes substituted in the 3 position with bulky silyl groups (TMS, TBDMS) have been synthesized. Although some of these complexes catalyzed the epoxidation of unfunctionalized olefins in moderate to high ee's, they catalyzed the aziridination of cis-beta-methylstyrene without any asymmetric induction.

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页码：1001 / 1004

页数：4

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