LIQUID LIQUID EQUILIBRIA OF THE TERNARY-SYSTEM WATER PLUS PROPANOIC ACID PLUS METHYL ISOBUTYL KETONE AT VARIOUS TEMPERATURES

被引：55

作者：

ARCE, A

BLANCO, A

SOUZA, P

VIDAL, I

机构：

[1] Department of Chemical Engineering, University of Santiago de Compostela

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1993年 / 38卷 / 02期

关键词：

D O I：

10.1021/je00010a003

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid equilibrium data are reported for the binary system water + methyl isobutyl ketone over the range 20-55-degrees-C and for the ternary system water + propanoic acid + methyl isobutyl ketone at 25, 35, 45, and 55-degrees-C. The NRTL and UNIQUAC equations have been fitted to the experimental data by optimizing their system-specific parameters; the goodness of fit is satisfactory in both cases.

引用

收藏

页码：201 / 203

页数：3

相关论文

共 11 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2] LIQUID LIQUID EQUILIBRIA OF THE SYSTEM WATER + ACETIC-ACID + METHYL ISOPROPYL KETONE BETWEEN 25-DEGREES-C AND 55-DEGREES-C [J].

CORREA, JM ;

BLANCO, A ;

ARCE, A .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :415-419

[3] Aqueous solubilities of some aliphatic ketones [J].

Ginnings, PM ;

Plonk, D ;

Carter, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1923-1924

[4] Energy and volume relations in the solubilities of some ketones in water [J].

Gross, P ;

Rintelen, JC ;

Saylor, JH .

JOURNAL OF PHYSICAL CHEMISTRY, 1939, 43 (02) :197-205

[5]

HLAVATY K, 1940, COLLECT CZECH CHEM C, V38, P374

[6]

IGUCHI A, 1971, KAGAKU KOGAKU, V35, P477

[7] UNIFAC PARAMETER TABLE FOR PREDICTION OF LIQUID-LIQUID EQUILIBRIA [J].

MAGNUSSEN, T ;

RASMUSSEN, P ;

FREDENSLUND, A .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1981, 20 (02) :331-339

[8] LIQUID LIQUID-PHASE EQUILIBRIA IN THE PROPYLENE CARBONATE + METHYL ISOBUTYL KETONE + WATER-SYSTEM [J].

RAJAPAKSE, N ;

FINSTON, HL ;

FRIED, V .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (04) :408-410

[9] LOCAL COMPOSITIONS IN THERMODYNAMIC EXCESS FUNCTIONS FOR LIQUID MIXTURES [J].

RENON, H ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1968, 14 (01) :135-+

[10] Extraction in spray and packed columns [J].

Sherwood, TK ;

Evans, JE ;

Longcor, JVA .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1939, 31 :1144-1150