DESIGN OF ZR(IV) AND HF(IV) COORDINATION-COMPOUNDS - PRECURSORS FOR MOCVD SYNTHESIS OF PROTECTIVE COATINGS

被引：7

作者：

GRAFOV, A ^{[1
]}

MAZURENKO, E ^{[1
]}

BATTISTON, GA ^{[1
]}

ZANELLA, P ^{[1
]}

机构：

[1] CNR,INST INORGAN TECHNOL & ADV MAT,I-35020 PADUA,ITALY

来源：

JOURNAL DE PHYSIQUE IV | 1995年 / 5卷 / C5期

关键词：

D O I：

10.1051/jphyscol:1995557

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Design and creation of new materials with unusual, predictable or predeterminated properties become one of the most actual problems of modem applied chemistry. Main demands are discussed, which are made to chemical compounds used in CVD synthesis of functional materials. A division of volatile metal-containing precursors into main classes is given. On the basis of volatility and thermal stabiliti criteria elaborated at IGIC-NASU, we have designed synthesized and characterized a series of new advanced precursors for Zr(IV) and Hf(IV). Their properties are compared to those of known species. A possibility of formation of requested properties and structure of final materials is shown.

引用

页码：497 / 502

页数：6