IMPACT IONIZATION IN PROTON-H-ATOM-SYSTEM .3. ELECTRON TRANSLATION FACTOR AND TRANSITION OPERATORS

被引：45

作者：

LEVY, H

THORSON, WR

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

[2] Department of Chemistry, University of Alberta, Edmonton, Alta.

[3] Smithsonian Astrophysical Observatory, Cambridge

来源：

PHYSICAL REVIEW | 1969年 / 181卷 / 01期

关键词：

D O I：

10.1103/PhysRev.181.252

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

To meet asymptotic boundary conditions, the scattering wave function for an atomic collision must include a kinematic factor representing transport of an electron attached to a moving heavy particle. For slow collisions this factor grossly affects the inelastic transition operator and its matrix elements. The general conditions the factor must satisfy are discussed. Matrix elements for impact ionization are especially sensitive to the choice of the factor, and computed results obtained with several choices are described briefly. A heuristic criterion for systematic improvement of the factor is discussed. © 1969 The American Physical Society.

引用

页码：252 / &

共 10 条

[1] ELECTRON CAPTURE IN SLOW COLLISIONS [J].

BATES, DR ;

MCCARROLL, R .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1958, 245 (1241) :175-183

[2] CALCULATION OF THE COUPLING TERMS NEGLECTED IN PERFORMING THE BORN-OPPENHEIMER SEPARATION FOR THE HYDROGEN MOLECULE ION [J].

JEPSEN, DW ;

HIRSCHFELDER, JO .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (05) :1323-1335

[3] IMPACT IONIZATION IN PROTON-H-ATOM SYSTEM .2. ELECTRONIC STATES AND TRANSITION ELEMENTS [J].

LEVY, H ;

THORSON, WR .

PHYSICAL REVIEW, 1969, 181 (01) :244-&

[4]

Messiah A., 1962, QUANTUM MECHANICS, V2

[5] PROTON-HYDROGEN SCATTERING SYSTEM [J].

MITTLEMAN, M .

PHYSICAL REVIEW, 1961, 122 (02) :499-&

[6]

MOTT NF, 1949, THEORY ATOMIC COLLIS, P153

[7]

SCHNEIDERMAN SB, 1967, THESIS U CONNECTICUT

[8]

SMITH K, 1967, ATOMATOM SCATTERING, V46

[9] THEORY OF SLOW ATOMIC COLLISIONS .I. H2+ [J].

THORSON, WR .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (11) :3878-&

[10] IMPACT IONIZATION IN PROTON-H-ATOM SYSTEM .I. THEORY [J].

THORSON, WR ;

LEVY, H .

PHYSICAL REVIEW, 1969, 181 (01) :230-&

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