HIGHLY SELECTIVE HETEROGENEOUS PALLADIUM-CATALYZED HYDROGENATIONS USING TRIETHOXYSILANE AND WATER

被引：52

作者：

TOUR, JM

COOPER, JP

PENDALWAR, SL

机构：

[1] Department of Chemistry, University of South Carolina, Columbia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 11期

关键词：

D O I：

10.1021/jo00298a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alkenes or alkynes at ambient temperature with triethoxysilane and 5 mol % of palladium^) acetate in a mixture of tetrahydrofuran and water affords the corresponding hydrogenated products. Excellent chemoselectivities and stereoselectivities can be obtained using this process. © 1990, American Chemical Society. All rights reserved.

引用

页码：3452 / 3453

页数：2

共 39 条

[1]

[Anonymous], 1985, HYDROGENATION METHOD

[2]

[Anonymous], 1975, STRUCTURE METALLIC C

[3]

Birch A., 1976, ORG REACT, V24, P1

[4]

BOUDART M, 1965, J CATAL, V4, P704