COMPLEXES OF NITROGEN-CONTAINING CROWN ETHER SURFACTANTS WITH STABLE SILVER ATOMS

被引:43
作者
HUMPHRYBAKER, R
GRATZEL, M
TUNDO, P
PELIZZETTI, E
机构
[1] ECOLE POLYTECH FED LAUSANNE,INST CHIM PHYS,CH-1015 LAUSANNE,SWITZERLAND
[2] UNIV TURIN,IST CHIM ANAL,I-10126 TURIN,ITALY
[3] UNIV TURIN,IST CHIM ORGAN,I-10126 TURIN,ITALY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期
关键词
D O I
10.1002/anie.197906301
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photochemical reduction of complexed Ag+ ions to stable complexed Ag atoms can be accomplished with the aid of the heterocycle 1, which combines the properties of a crown ether and of a surfactant. 1 Ag+ is formed spontaneously from 1 and AgNO3; reduction with visible light requires a cyanine dye as sensitizer. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
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页码:630 / 631
页数:2
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