THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION

被引：15

作者：

COMPTON, RG

FISHER, AC

TYLEY, GP

机构：

[1] Physical Chemistry Laboratory, Oxford University, OXFORD, OX1 3QZ, South Parks Road

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1990年 / 20卷 / 06期

关键词：

D O I：

10.1007/BF01019565

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of characterizing the EC mechanism. A working curve is presented which permits the analysis of experimental data and the deduction of the rate constant for the following chemical reaction. © 1990 Chapman and Hall Ltd.

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页码：912 / 915

页数：4

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