CATIONS WITH XENON CARBON BONDS .4. SALTS WITH MONOSUBSTITUTED PHENYL XENON CATION - PREPARATION, STABILITY AND REACTIVITY

被引：20

作者：

FROHN, HJ

ROSSBACH, C

机构：

[1] Fachgebiet Anorganische Chemie Der Universität, Duisburg

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 10期

关键词：

XENON-CARBON BOND; PHENYLXENON CATION; F-SUBSTITUTED AND CF3-SUBSTITUTED PHENYLBORANES; FLUOROPHENYLBORANES AND FLUOROPHENYLBORATES;

D O I：

10.1002/zaac.19936191006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nucleophilic fluorine aryl substitution reactions with monosubstituted phenylboranes (X-C6H4)3B and fluorophenylboranes (X-C6H4)nBF3-n (n = 1 and 2; X = m-F, p-F, m-CF, and p-CF3) on XeF2 lead to the formation of [X-C6H4Xe]+ salts with arylfluoroborate anions [(X-C6H4)nBF4-n]- (n = 2, 1 and 0). Their thermal behaviour, their spectroscopic properties and first investigations concerning their reactivity are reported.

引用

页码：1672 / 1678

页数：7

共 17 条

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