ADSORPTION BEHAVIOR OF END-FUNCTIONALIZED POLYMERS MODIFIED BY IMINIUM ION

In order to clarify the end-functionalization effect of polymers modified by iminium ion, a model compound with a modified chain end was prepared by directly reacting n-butyllithium with N-methyl-2-pyrrolidone and then quenching by the addition of methanol. It is shown that the model compound includes the iminium ion group and that the adsorption bands in the IR-spectra of the chemically modified polymer were similar to those of model compound. The adsorption behavior of end-functionalized polystyrene(PS-X) and diblock copolymer of PS and polybutadiene(PB) which were modified by iminium ion(PS-PB-X), were examined over a wide range of molecular weights of these polymers. It is evident that the amount of adsorption increased significantly by the end-functionalization and this trend was especially strong in the low molecular weight polymers (M(W) less than or equal to 10(5)). The preference for the end-functionalized polymer was also examined by competitive and sequential adsorption experiments between different molecular weight species. It is shown that a prefered adsorption of PS-X with low molecular mass is pronounced over the adsorption of PS or PS-X with high molecular weight and in the combination of high and low molecular weight species of PS-X, a special enhancement of total adsorption can be observed. This enhancement is based on a combination of different adsorption layers formed by these two molecular weight species.