UNSATURATION OF KETONES, NITRILES AND LACTAMS WITH METHYL PHENYLSULFINATE

被引:55
作者
RESEK, JE [1 ]
MEYERS, AI [1 ]
机构
[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523
基金
美国国家卫生研究院;
关键词
D O I
10.1016/0040-4039(95)01461-P
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An improved synthesis of methyl phenylsulfinate 2 by treatment of diphenyl disulfide with bromine in the presence of methanol has been developed. Use of this reagent in the preparation of alpha,beta-unsaturated ketones, nitriles and lactams is described.
引用
收藏
页码:7051 / 7054
页数:4
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