Asymmetric induction in the palladium-catalyzed nucleophilic substitution reactions of chiral beta-sulfinylallylic systems

被引：17

作者：

Hiroi, K

Onuma, H

Arinaga, Y

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 12期

关键词：

D O I：

10.1246/cl.1995.1099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of the palladium-catalyzed asymmetric nucleophilic substitutions of chiral beta-sulfinylallylic systems is described. The degree of the asymmetric induction was dependent on the reaction conditions, especially a phosphine ligand used. The plausible mechanism of the asymmetric induction is proposed on the basis of the stereochemical results obtained.

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页码：1099 / 1100

页数：2

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