THERMAL-DECOMPOSITION OF BRANCHED-CHAIN PERFLUOROALKANES

被引：22

作者：

TORTELLI, V ^{[1
]}

TONELLI, C ^{[1
]}

CORVAJA, C ^{[1
]}

机构：

[1] UNIV PADUA,DEPT PHYS CHEM,I-35131 PADUA,ITALY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 2-3期

关键词：

D O I：

10.1016/S0022-1139(00)80030-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pyrolysis of some branched perfluoroalkanes has been studied. Homolytic cleavage of the most hindered carbon-carbon bond occurs, followed by coupling and rearrangement of the radicals so formed. This mechanism accounts for all the reaction products. Some kinetic and thermodynamic data are presented.

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页码：165 / 174

页数：10

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