TOWARDS SYNTHETIC ENZYMES BASED ON PORPHYRINS AND STEROIDS

被引：67

作者：

BONARLAW, RP

MACKAY, LG

WALTER, CJ

MARVAUD, V

SANDERS, JKM

机构：

[1] Cambridge Centre for Molecular Recognition, University Chemical Laboratory, Cambridge CB2 1EW, Lensfield Road

来源：

PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 04期

关键词：

D O I：

10.1351/pac199466040803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular recognition properties of three systems are discussed: a self-associating cyclocholate; a porphyrin-cyclocholate molecular bowl which recognises morphine enantioselectively; and a cyclic porphyrin trimer which efficiently and stereoselectively accelerates a Diels-Alder reaction.

引用

页码：803 / 810

页数：8

共 12 条

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[8] OPTICALLY-ACTIVE MONO AND BIS(1,1'-BINAPHTHYL)-CYCLOPHANES - LARGE DIFFERENCES IN THE COMPLEXATION OF NAPROXEN DERIVATIVES IN AQUEOUS-SOLUTION
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