Control of hydrogen bonding in the design of new diol lattice inclusion compounds

被引:25
作者
Bishop, Roger [1 ]
Craig, Donald C. [1 ]
Dance, Ian G. [1 ]
Kim, Sungho [1 ]
Mallick, Md. Aminul I. [1 ]
Pich, Kim C. [1 ]
Scudder, Marcia L. [1 ]
机构
[1] Univ New S Wales, Sch Chem, Kensington, NSW 2033, Australia
基金
澳大利亚研究理事会;
关键词
D O I
10.1080/10610279308040663
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to be able to predict and then synthesize new lattice inclusion compounds with the helical tubuland diol host structure, the hydrogen bonding modes of a range of bicyclic and tricyclic diols have been studied using X-ray crystallography. Several distinct types of lattice structure have been recognized. Steric factors play a major role in determining which of these is produced in a given case. Establishment of a series of structural rules provides a window of opportunity for duplication of the helical tubuland host lattice by deliberate design and synthesis. New inclusion compounds resulting from this approach are presented.
引用
收藏
页码:171 / 178
页数:8
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