CHEMISTRY OF TRIFLUORAMINE OXIDE .3. LEWIS ACID COMPLEXES OF F3NO . STRUCTURE AND REACTIONS OF F2NO+ ION

被引：22

作者：

WAMSER, CA

FOX, WB

SUKORNIC.B

HOLMES, JR

STEWART, BB

JUURIK, R

VANDERKO.N

GOULD, D

机构：

[1] Industrial Chemicals Division, Allied Chemical Corporation, Morristown

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 06期

关键词：

D O I：

10.1021/ic50076a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of F3NO with the Lewis acids BF3, AsF5, and SbF5 were found to exist in the ionic form F2NO+A-, where A- = BF4-, AsF6-, or SbF6-. Infrared spectra of the solid complexes as well as infrared, nmr, and conductivity studies of the complexes dissolved in polar fluorinated solvents confirm their ionic constitution and indicate that the F2NO+ cation exhibits the same planar geometry as the isoelectronic COF2 molecule. © 1969, American Chemical Society. All rights reserved.

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页码：1249 / &

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