REACTIVE SCATTERING OF B+(P-3(U) BY MOLECULAR DEUTERIUM

被引:21
作者
SONDERGAARD, NA
SAUERS, I
JONES, AC
KAUFMAN, JJ
KOSKI, WS
机构
[1] Department of Chemistry, Johns Hopkins University, Baltimore
关键词
D O I
10.1063/1.438555
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The angular and energy distribution of the ionic products from the reaction of B+ in its first excited state, 3Pu, with molecular deuterium was studied over a projectile energy range of 1 to 40 eV in the laboratory system. The product states as determined from the limiting values of the translational exoergicity were BD+ (2∑ +) and BD+ (2Π). The experimental velocity contour maps indicated that BD+(2∑+) was arising through complex formation whereas BD+ (2Π) was proceeding by a direct mechanism. © 1979 American Institute of Physics.
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收藏
页码:2229 / 2234
页数:6
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