THE DIELS-ALDER REACTION OF CYCLOPENTADIENE AND METHYL ACRYLATE ON GAMMA-ALUMINA

被引：66

作者：

HONDROGIANNIS, G ^{[1
]}

PAGNI, RM ^{[1
]}

KABALKA, GW ^{[1
]}

ANOSIKE, P ^{[1
]}

KURT, R ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 38期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)97865-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of cyclopentadiene and methyl acrylate has been run on γ-alumina. The ratio of endo to exo products is strongly dependent on the activity of the alumina. The exo adduct was also found to epimerize slowly to the endo adduct by a mechanism involving the retro-Diels-Alder reaction of the exo adduct. © 1990.

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页码：5433 / 5436

页数：4

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