ASYMMETRIC CYCLOPALLADATION OF DIMETHYLAMINOMETHYLFERROCENE

被引：210

作者：

SOKOLOV, VI

TROITSKAYA, LL

REUTOV, OA

机构：

[1] Institute of Organo-Element Compounds, Moscow

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 04期

关键词：

D O I：

10.1016/S0022-328X(00)83942-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladation of dimethylaminomethylferrocene (I) catalyzed by salts of optically active acids affords optically active planar chiral 2-dimethylaminomethylferrocenylpalladium chloride dimer (II) in high yield. Absolute rotation and optical purity of II were determined by conversion to 2-methylferrocenecarboxylic acid and 2-methylferrocenealdehyde. Factors affecting enantiomeric excess are examined and conditions for maximal asymmetric induction are found. © 1979.

引用

页码：537 / 546

页数：10

共 36 条

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