THE REACTION OF OPTICALLY-ACTIVE MENTHYL ACRYLATE WITH CYCLOPENTADIENE ON GAMMA-ALUMINA

被引：24

作者：

HONDROGIANNIS, G ^{[1
]}

PAGNI, RM ^{[1
]}

KABALKA, GW ^{[1
]}

KURT, R ^{[1
]}

COX, D ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 21期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)79909-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of optically active menthyl acrylate with cyclopentadiene is catalyzed by gamma-alumina. The reaction is very selective, yielding large endo to exo ratios of products and diasteroemeric excesses for the endo adduct.

引用

页码：2303 / 2306

页数：4

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