COPPER MONOOXYGENASE MODELS - HYDROXYLATION REACTIONS RESULTING FROM DIOXYGEN ACTIVATION BY COPPER(I) COMPLEXES

被引:23
作者
AMADEI, E [1 ]
ALILOU, EH [1 ]
EYDOUX, F [1 ]
PIERROT, M [1 ]
REGLIER, M [1 ]
WAEGELL, B [1 ]
机构
[1] FAC SCI & TECH ST JEROME,LASCO,CNRS,URA 1409,AVE ESCADRILLE NORMANDIE NIEMEN,CASE 532,F-13397 MARSEILLE 13,FRANCE
关键词
D O I
10.1039/c39920001782
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe the synthesis and reactivity of new mononuclear copper(I) complexes 4a-c, which can be considered to be copper monooxygenase models and can be used to achieve hydroxylation of aliphatic C-H bonds by dioxygen activation.
引用
收藏
页码:1782 / 1784
页数:3
相关论文
共 42 条