STEREOCHEMISTRY AND REGIOCHEMISTRY OF HETEROATOM DIRECTED REACTIONS .5. THE 1ST PRACTICAL METHOD OF SELECTIVE HETEROATOM-DIRECTED CHLOROHYDROXYLATION

被引：28

作者：

LAI, JY ^{[1
]}

WANG, FS ^{[1
]}

GUO, GZ ^{[1
]}

DAI, LX ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMETALL CHEM LAB,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 25期

关键词：

D O I：

10.1021/jo00077a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new Pd(II)-catalyzed nucleophilic chlorohydroxylation reaction of allylic amines and sulfides was achieved, and the regioselective reaction gives high yields of the chlorohydrin products, which can be transformed into epoxy compounds or aziridine compounds by simple manipulations.

引用

页码：6944 / 6946

页数：3

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