SYNTHESIS AND CRYSTAL-STRUCTURE OF [LICL.2THF]2

被引：49

作者：

HAHN, FE

RUPPRECHT, S

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 02期

关键词：

CRYSTAL STRUCTURE; LITHIUM CHLORIDE THF ADDUCT;

D O I：

10.1515/znb-1991-0203

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of lithiated catechol ligands with W(O)Cl4 produces LiCl as a side product. The lithiumchloride from this reaction crystallizes as (THF)2Li(mu-Cl)2Li(THF)2. The X-ray analysis shows lithium in the center of a distorted tetrahedron made up from two THF molecules and two bridging chlorides with d(Li-Cl) = 2.342(3) and 2.308(3) angstrom.

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页码：143 / 146

页数：4

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