ALKYL HYDROPEROXIDE OXIDATION OF ALKANES AND ALKENES WITH A HIGHLY-ACTIVE MN CATALYST

被引：48

作者：

SARNESKI, JE

MICHOS, D

THORP, HH

DIDIUK, M

POON, T

BLEWITT, J

BRUDVIG, GW

CRABTREE, RH

机构：

[1] FAIRFIELD UNIV,DEPT CHEM,FAIRFIELD,CT 06430

[2] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92031-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The system ROOH/[Mn3O4(dipy)4(OH2)2](ClO4)4 hydroxylates alkanes and converts ArCR = CH2 to ArCR = O with extremely high activity and good conversions and yields.

引用

页码：1153 / 1156

页数：4

共 13 条

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