PENTAFLUOROPHENYLXENON(II) PENTAFLUOROBENZOATE - THE 1ST PREPARATIVE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF AN ACYLOXY COMPOUND OF XENON(II)

被引：29

作者：

FROHN, HJ

KLOSE, A

HENKEL, G

机构：

[1] Fachgebiet Anorganische Chemie, Universität Duisburg, D-W-4100

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 01期

关键词：

D O I：

10.1002/anie.199300991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unexpectedly stable, 3, a covalent acyloxy compound of xenon(II), only decomPoses at 85-degrees-C and can be stored almost indefinitely as a solid at room temperature and in CH2Cl2 at -45-degrees-C. Compound 3 is formed from the arylxenon salt 1 and the cesium salt 2 in water (!); in the crystal it is characterized by a linear arrangement of O, Xe, and C, as well as by a ''dimerization'' through Xe2O2 rings. [GRAPHICS]

引用

页码：99 / 100

页数：2

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