RECONSTITUTION OF MYOGLOBIN WITH A HEME COFACTOR BEARING A RUTHENIUM TRIS(2,2'-BIPYRIDINE) PENDANT

被引：16

作者：

HAMACHI, I

TANAKA, S

SHINKAI, S

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A protoheme derivative with covalently-bound tris(2,2'-bipyridine) ruthenium (11) [Ru(bpy)3]2+ was successfully incorporated into apo-myoglobin. In the reconstituted myoglobin emission of *[Ru(bpy)3]2+ was quenched intramolecularly, the efficiency being greater by more than 30-fold than that of the corresponding intermolecular process.

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页码：1417 / 1420

页数：4

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