AROMATIC REACTIVITY .41. AN ANALYSIS OF SUBSTITUENT EFFECTS IN DETRITIATION OF 1- AND 2-TRITIONAPHTHALENES

被引:20
作者
EABORN, C
FISCHER, A
机构
[1] School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ, Sussex
来源
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 02期
关键词
D O I
10.1039/j29690000152
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The effects of substituents on the rates of detritiation at the 1- and 2-position of naphthalene are examined in terms of various substituent constants. An empirical analysis of the separate transmission of polar and resonance effects indicates that the theoretical charge distribution in the Wheland intermediate provides the best simple guide to the substituent influences from the various positions.
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页码:152 / &
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