Chemical Reactions--Redox - Electrodes;
Electrochemical--Performance;
-;
Electrodes--Materials;
Polymers--Electrochemistry;
D O I:
10.1016/0167-2738(88)90309-8
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The poly(decaviologen) (DV2+, 2 ClO4-) has been investigated in contact with PEO-LiClO4 electrolyte. Two distinct redox couples based upon the dication and radical cation as reduced form have been distinguished. This electrode was suitable for the measure of the lithium transference number which was found to be close to 0.2. Other ionic transport parameters have been measured as well.