BOWLANE (TETRACYCLO (3.3.3.13.1017.10) TRIDECANE) - A NEW HYPOTHETICAL MOLECULE POSSESSING A PYRAMIDAL TETRACOORDINATED CARBON-ATOM IN THE GROUND-STATE

被引：26

作者：

DODZIUK, H

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 239卷

关键词：

D O I：

10.1016/0022-2860(90)80210-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new hypothetical molecule, tetracyclo [3.3.3.13,1017,10]tridecane, named bowlane, which should possess a pyramidal carbon atom in the ground state, is proposed. The influence of ring enlargement on the pyramidality of the central atom is estimated on the basis of molecular mechanics. The difference between inverted and pyramidal carbon atoms is briefly discussed and a measure of planarization and pyramidality of a tetracoordinated carbon atom is proposed. © 1990.

引用

页码：167 / 172

页数：6

共 26 条

[1] STABILIZATION OF PLANAR TETRACOORDINATE CARBON
COLLINS, JB
DILL, JD
JEMMIS, ED
APELOIG, Y
SCHLEYER, PV
SEEGER, R
POPLE, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) : 5419 - 5427
[2] CRANS DC, 1980, J AM CHEM SOC, V102, P7153
[3] DODZIUK H, 1987, B POL ACAD SCI-CHEM, V35, P195
[4] THE STUDY OF PLANARIZED AND PLANAR CYCLOHEXANE RINGS ON THE BASIS OF MOLECULAR MECHANICS
DODZIUK, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (10) : 3775 - 3779
[5] DODZIUK H, 1988, TETRAHEDRON, V44, P2951
[6] DODZIUK H, IN PRESS B ACAD SCI
[7] CALCULATIONS ON LOWEST ENERGY STATE OF PLANAR METHANE
DURMAZ, S
PEDLEY, JB
MURRELL, JN
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (16) : 933 - &
[8] TOWARD TRICYCLO[2.2.2.2]DECANE .1. [N.2.2.2]PADDLANE SYSTEMS, N = 10-14
EATON, PE
LEIPZIG, BD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (06) : 1656 - 1658
[9] Greenberg A., 1978, STRAINED ORGANIC MOL, V1st
[10] PLANAR TETRACOORDINATE CARBON
HOFFMANN, R
ALDER, RW
WILCOX, CF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) : 4992 - &

← 1 2 3 →