ABSOLUTE-CONFIGURATION OF 1-METHYLINDANE

被引:38
作者
HANSEN, HJ [1 ]
SLIWKA, HR [1 ]
HUG, W [1 ]
机构
[1] UNIV FRIBOURG,INST PHYS CHEM,CH-1705 FRIBOURG,SWITZERLAND
关键词
D O I
10.1002/hlca.19790620422
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
It is shown unequivocally by chemical correlations (cf. Schemes 1‐‐3) and Raman optical activity spectra (cf. Fig. 1 and 2) that the (R)‐configuration has to be attributed to (+)‐1‐methylindane ((+)‐1). This is in contradiction to an earlier assignment of the (R)‐configuration to (−)‐1[2] which was based on the (R)‐configuration of (+)‐indane‐1‐carboxylic acid (3) [11]. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim
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页码:1120 / 1128
页数:9
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