PALLADIUM-CATALYZED NORBORNENE CARBON-MONOXIDE COOLIGOMERIZATION INITIATED BY ARYL GROUPS AND TERMINATED BY DOUBLE-BOND FORMATION

被引：17

作者：

DALCANALE, E

AN, Z

BATTAGLIA, LP

CATELLANI, M

CHIUSOLI, GP

机构：

[1] UNIV PARMA,IST CHIM ORGAN,VIALE SCI,I-43100 PARMA,ITALY

[2] UNIV PARMA,IST CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 437卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)85082-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of m-iodophenol as initiator in palladium-catalyzed norbornene-carbon monoxide oligomerization in the presence of potassium acetate unexpectedly leads to termination by double bond formation in spite of the limitations to beta-H-anti elimination. The presence of endo products points to preliminary exo-to-endo isomerization through enolization. The X-ray structure of one stereoisomer (Ia) is given.

引用

页码：375 / 388

页数：14

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