PREDICTION OF THE STOICHIOMETRY OF CATION-RADICAL SALTS OF ORGANIC METALS BY THIN-LAYER CYCLIC VOLTAMMETRY

被引：17

作者：

CARLIER, R

FRERE, P

SALLE, M

RONCALI, J

JUBAULT, M

TALLEC, A

GORGUES, A

机构：

[1] UNIV RENNES 1,ELECTROCHIM LAB,CNRS,URA 439,F-35042 RENNES,FRANCE

[2] LAB MAT MOLEC,CNRS,UPR 241,F-94320 THIAIS,FRANCE

来源：

ADVANCED MATERIALS | 1993年 / 5卷 / 06期

关键词：

D O I：

10.1002/adma.19930050606

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The detection of mixed valences in organic metals using thin layer cyclic voltammetry is reported. Although mixed valence is recognized as a prerequisite for superconductivity in cation radical salts this is the first report of a method which enables the reliable prediction of the conditions necessary for the production of a suitable cation radical stoichiometry. The method and its application to TTF derivatives are described. Copyright © 1993 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：445 / 447

页数：3

共 30 条

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