CARBON-SULFUR BOND-CLEAVAGE BY COBALT - REACTION OF CP-ASTERISK-CO(C2H4)2 WITH DIBENZOTHIOPHENE

被引：49

作者：

JONES, WD

CHIN, RM

机构：

[1] Department of Chemistry, University of Rochester, Rochester

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 472卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

COBALT; CYCLOPENTADIENYL; THIOLATE; THIOPHENE; CRYSTAL STRUCTURE; DESULFURIZATION;

D O I：

10.1016/0022-328X(94)80217-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal reaction of Cp*Co(C2H4)2 with thiophene yields the C-S insertion product [CP*Co]2(mu-eta2,eta3-C4H4S). Reaction with dibenzothiophene produces the analogous dinuclear C-S insertion adduct [CP*Co]2(mu-eta2,eta3-C12H8S) the crystal structure of which was determined. Reaction of the thiophene insertion adduct with H2S gives a new butadienedithiolate compound in which sulfur has inserted into the metal-carbon bond, [CP*Co]2(mu-eta2,eta2-S2C4H4).

引用

页码：311 / 316

页数：6

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