TRANS-EFFECT AND TRANSINFLUENCE SERIES FOR PHOSPHANES IN OCTAHEDRAL ENVIRONMENT - A GUIDE FOR DESIGN OF NEW CATALYSTS

被引：14

作者：

DONASCIMENTO, JC

DELIMA, JB

NETO, BDL

FRANCO, DW

机构：

[1] USP,INST FIS & QUIM SAO CARLOS,CP 369,BR-13560 SAO CARLOS,SP,BRAZIL

[2] UNIV FED RIO GRANDE NORTE,NATAL,RN,BRAZIL

[3] UNIV FED MARANHAO,SAO LUIS,MARANHAO,BRAZIL

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 90卷 / 03期

基金：

巴西圣保罗研究基金会;

关键词：

OCTAHEDRAL ENVIRONMENT; PHOSPHANES; RUTHENIUM;

D O I：

10.1016/0304-5102(94)00018-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By a kinetic approach, the trans-effects and trans-influences of nineteen tertiary phosphane ligands were evaluated for a hexacoordinated d6-low spin metal center. Plots of specific rate constants versus formal potentials for Ru(III)/Ru(II) couples provide a simple, reliable and efficient method to predict phosphane reactivity and are useful as a guide for design of new catalysts.

引用

收藏

页码：257 / 266

页数：10

相关论文

共 60 条

[1] THE BASICITY OF PHOSPHINES [J].

ALLMAN, T ;

GOEL, RG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (06) :716-722

[2] THE NATURE OF PHOSPHORUS(III) LIGANDS AS PROBED BY MO-95 NMR-SPECTROSCOPY [J].

ALYEA, EC ;

SONG, SQ .

INORGANIC CHEMISTRY, 1992, 31 (24) :4909-4910

[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[4] AXIAL-LIGAND SUBSTITUTION-REACTIONS OF DIRHODIUM(II) TETRAACETATE WITH PHOSPHINES AND PHOSPHITES IN ACETONITRILE [J].

AQUINO, MAS ;

MACARTNEY, DH .

INORGANIC CHEMISTRY, 1987, 26 (16) :2696-2699

[5] BIS(DIOXOLENE)BIS(PYRIDINE)RUTHENIUM REDOX SERIES [J].

AUBURN, PR ;

DODSWORTH, ES ;

HAGA, M ;

LIU, W ;

NEVIN, WA ;

LEVER, ABP .

INORGANIC CHEMISTRY, 1991, 30 (18) :3502-3512

[6]

BABKO AK, 1971, PHOTOCHEMETRIC ANAL

[7] EFFECT OF A SERIES OF PHOSPHINE AND PHOSPHITE LIGANDS ON THE TAFT SUBSTITUENT CONSTANTS OF ARENECHROMIUMCARBONYL AND CYCLOPENTADIENYLMANGANESECARBONYL COMPLEXES [J].

BITTERWOLF, TE .

POLYHEDRON, 1988, 7 (05) :409-415

[8] TRANS INFLUENCE AND MUTUAL INFLUENCE OF LIGANDS COORDINATED TO A CENTRAL ATOM [J].

BURDETT, JK ;

ALBRIGHT, TA .

INORGANIC CHEMISTRY, 1979, 18 (08) :2112-2120

[9] SYSTEMATIC SUBSTITUENT EFFECTS ON DISSOCIATIVE SUBSTITUTION KINETICS OF RU(CO)4P-DONOR, RU(CO)4AS-DONOR, AND RU(CO)4AS-DONOR LIGANDS [J].

CHEN, L ;

POE, AJ .

INORGANIC CHEMISTRY, 1989, 28 (19) :3641-3647

[10]

CONSTABLE EC, 1990, METAL LIGAND REACTIV

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