NUCLEOPHILIC-SUBSTITUTION BETWEEN A GASEOUS ALKYL HALIDE AND A SOLID SALT, PROMOTED BY PHASE-TRANSFER CATALYSTS

被引：45

作者：

TUNDO, P

机构：

[1] Istituto di Chimica Orgnica dellUniversita, 36-10125 Torino, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 12期

关键词：

D O I：

10.1021/jo01326a042

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By passing a gaseous alkyl halide over a catalytic column composed of a salt, a solid support, and a phasetransfer catalyst, the substitution product is obtained. The phase-transfer catalyst can be either free or immobilized on a silica matrix; in this way syntheses of alkyl iodides and esters are possible. © 1979, American Chemical Society. All rights reserved.

引用

页码：2048 / 2049

页数：2

共 5 条

[1] FUSED ORGANIC SALTS .3. CHEMICAL STABILITY OF MOLTEN TETRA-N-ALKYLAMMONIUM SALTS . MEDIUM EFFECTS ON THERMAL R4N+X- DECOMPOSITION . RBR + I- = RI + BR- EQUILIBRIUM CONSTANT IN FUSED SALT MEDIUM [J].