CONCERNING THE QUESTIONABLE EXISTENCE OF THIOXOINDIGOID COMPOUNDS

被引：39

作者：

SCHROTH, W ^{[1
]}

HINTZSCHE, E ^{[1
]}

FELICETTI, M ^{[1
]}

SPITZNER, R ^{[1
]}

SIELER, J ^{[1
]}

KEMPE, R ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,O-7010 LEIPZIG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1002/anie.199407391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neither in the solid state, nor in solution—proof of the existence of indigoid compounds such as 1 with thioxo instead of oxo groups remains elusive. The oxidation of leucoindigoid precursors does not lead to 1 in any example examined, but rather to the valence isomeric 1,2‐dithiines 2 or to macrocyclic bisdisulfides, depending on the heteroatom X (S, NCH3, NH, O). (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：739 / 741

页数：3

共 49 条

[1]

BEHRINGER H, 1981, LIEBIGS ANN CHEM, P1928

[2]

BEHRINGER H, 1982, LIEBIGS ANN CHEM, P315

[3]

BEHRINGER H, 1981, LIEBIGS ANN CHEM, P1729

[4] SYNTHESIS OF 2,2'-BIINDOLYLS BY COUPLING REACTIONS [J].

BERGMAN, J ;

EKLUND, N .

TETRAHEDRON, 1980, 36 (10) :1439-1443

[5] POLYACETYLENVERBINDUNGEN .86. UBER ROTE NATURLICHE SCHWEFELACETYLENVERBINDUNGEN [J].

BOHLMANN, F ;

KLEINE, KM .

CHEMISCHE BERICHTE-RECUEIL, 1965, 98 (09) :3081-&

[6] QUANTUM CHEMICAL CALCULATIONS FOR STRUCTURE OF 1,2-DITHIIN [J].

BORSDORF, R ;

HOFMANN, HJ ;

KOHLER, HJ ;

SCHOLZ, M ;

FABIAN, J .

TETRAHEDRON, 1970, 26 (13) :3227-&

[7] MODEL CALCULATIONS ON THIOCARBONYL SYSTEMS [J].

CALZAFERRI, G ;

GLEITER, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (06) :559-566

[8] A RAPID PREPARATION OF 2,2'-DIMERCAPTOBIPHENYL [J].

COSSU, S ;

DELOGU, G ;

FABBRI, D ;

MAGLIOLI, P .

ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1991, 23 (04) :455-457

[9]

De Jong F., 1971, J ORG CHEM, V36, P1645

[10] 1,2-DITHIETE IS MORE STABLE THAN 1,2-DITHIOGLYOXAL AS EVIDENCED BY A COMBINED EXPERIMENTAL AND THEORETICAL IR SPECTROSCOPIC APPROACH [J].

DIEHL, F ;

MEYER, H ;

SCHWEIG, A ;

HESS, BA ;

FABIAN, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7651-7653

← 1 2 3 4 5 →