SOLID-STATE PHOTOCHEMISTRY - ABSOLUTE ASYMMETRIC OXETANE SYNTHESIS FROM AN ACHIRAL ACYCLIC IMIDE USING THE CHIRAL CRYSTAL ENVIRONMENT

被引：22

作者：

SAKAMOTO, M ^{[1
]}

TAKAHASHI, M ^{[1
]}

FUJITA, T ^{[1
]}

WATANABE, S ^{[1
]}

IIDA, I ^{[1
]}

NISHIO, T ^{[1
]}

AOYAMA, H ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 13期

关键词：

D O I：

10.1021/jo00065a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of chiral crystals of an achiral N-isopropyl-N-tiglylbenzoylformamide in the solid state proceeded [2 + 2] cycloaddition to give a chiral oxetane, 5,7-dimethyl-3-isopropyl-1-phenyl-6-oxa-3-azabicyclo[3.1.1]-heptane-2,4-dione, in high chemical and optical yields.

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页码：3476 / 3477

页数：2

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