SYNTHESIS, STRUCTURE, AND PROPERTIES OF LIWN2

被引：40

作者：

HERLE, PS ^{[1
]}

HEGDE, MS ^{[1
]}

VASANTHACHARYA, NY ^{[1
]}

GOPALAKRISHNAN, J ^{[1
]}

SUBBANNA, GN ^{[1
]}

机构：

[1] INDIAN INST SCI,MAT RES CTR,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 112卷 / 01期

关键词：

D O I：

10.1006/jssc.1994.1290

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis of a new ternary nitride LiWN2 by the reaction of Li2WO4 with NH3 at 745 degrees C. The compound crystallizes in a layered hexagonal structure with a = 2.863 and c = 15.608 Angstrom. LiWN2 is metallic, consistent with its structure with W(V) in trigonal prismatic coordination and Li1+ in octahedral coordination. (C) 1994 Academic Press, Inc.

引用

页码：208 / 210

页数：3

共 14 条

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