SYNTHESES IN ISOCAMPHANE SERIES .8. PREPARATION OF ENONES FROM 1-(3,3-DIMETHYL-2-NORBORNYL)-ETHANONE

被引：8

作者：

BUCHBAUER, G

KLISSENBAUER, E

机构：

[1] Pharmazeutisch-Chemisches Institut, Universität Wien, Wien, A-1090

来源：

MONATSHEFTE FUR CHEMIE | 1978年 / 109卷 / 02期

关键词：

D O I：

10.1007/BF00906369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of α,β-unsaturated ketones via the regiospecific aldol reaction of the title ketone with some aldehydes is described and their properties and spectra discussed. The exo-configuration at C-2 is retained in the bicyclic enones. The camphoraceous odour of the starting ketone is replaced by a floral-fruity odour of the enones. © 1978 Springer-Verlag.

引用

收藏

页码：499 / 510

页数：12

相关论文

共 15 条

[1] SYNTHESE UND KONFIGURATION DER CAMPHENILAN- UND DER ISOCAMPHENILANSAURE SOWIE DER AUS IHNEN ABGELEITETEN ALKOHOLE [J].

ALDER, K ;

ROTH, W .

CHEMISCHE BERICHTE-RECUEIL, 1957, 90 (09) :1830-1837

[2] SYNTHESIS OF DELTA-DAMASCONE [TRANS-1-(2,6,6-TRIMETHYLCYCLOHEX-3-ENYL)BUT-2-EN-1-ONE] AND BETA-DAMASCENONE [TRANS-1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIENYL)BUT-2-EN-1-ONE] [J].

AYYAR, KS ;

COOKSON, RC ;

KAGI, DA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (17) :1727-1736

[3]

BLOMBERG C, 1977, SYNTHESIS-STUTTGART, P18

[4] SYNTHESIS OF 1-(3,3-DIMETHYL-2-NORBORNYL)-ATHANON [J].

BUCHBAUER, G ;

HANA, GW ;

KOCH, H .

MONATSHEFTE FUR CHEMIE, 1976, 107 (02) :387-394

[5] SYNTHESIS OF POTENTIAL CHOLAGOGUES - STRUCTURE-ACTIVITY-RELATIONSHIPS OF BICYCLO[2.2.1]HEPTYL ALKYL CARBINOLS [J].

BUCHBAUER, G ;

HANA, GW ;

KOCH, H .

ARCHIV DER PHARMAZIE, 1978, 311 (01) :24-30

[6] SYNTHESES IN ISOCAMPHANE SERIES .7. SYNTHESIS OF ISOSANTALOL AND DELTA-SANTALOL [J].

BUCHBAUER, G .

MONATSHEFTE FUR CHEMIE, 1978, 109 (02) :289-302

[7] SYNTHESES IN ISOCAMPHANE SERIES .5. NEW SYNTHESIS OF CAMPHENILANIC ACID AND ISOCAMPHENILANE-CARBALDEHYDE [J].

BUCHBAUER, G .

MONATSHEFTE FUR CHEMIE, 1978, 109 (01) :3-9

[8]

DOEBNER O, 1902, BER, V35, P1137

[9] SYNTHESES OF DERIVATIVES OF ISOCAMPHENILANIC ACID [J].

HANA, GW ;

BUCHBAUER, G ;

KOCH, H .

MONATSHEFTE FUR CHEMIE, 1976, 107 (04) :945-948

[10]

KHUSNUTDINOV BS, 1940, UCHENYE ZAP KAZAN GO, V100, P189