ANHARMONICITY AND HYDROGEN BONDING ISOTOPIC SUBSTITUTION

被引:34
作者
ASSELIN, M
BELANGER, G
SANDORFY, C
机构
[1] Département de Chimie, Université de Montréal, Montréal, Que.
关键词
D O I
10.1016/0022-2852(69)90238-0
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The fundamentals and first overtones of the free and self-associated OH stretching bands of three alcohols and phenol were measured, the associated bands at liquid air temperature in rigid glasses. The dependence of the frequencies and anharmonicity constants on deuterium substitution was examined. The result is a new proof that hydrogen bonding has a profound influence on the anharmonicity of OH stretching vibrations. © 1969.
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页码:96 / &
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